You get the first piece of gear when you first scan the Amiibo. The second piece is unlocked after winning (not just playing) 10 games in any mode. Turf War or ranked both work. The third piece of gear is unlocked after winning another 10 matches. At 5 and 15 won games, they will hint at having found something for you, but you only get it at the 10th and 20th won game.
You don't need to save any data to the Amiibo to get the gear if you're starting from scratch in Splatoon 3.
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Re: Splatoon 3 amiibo Unlocks And Rewards - Full List
For those starting from scratch:
You get the first piece of gear when you first scan the Amiibo. The second piece is unlocked after winning (not just playing) 10 games in any mode. Turf War or ranked both work. The third piece of gear is unlocked after winning another 10 matches. At 5 and 15 won games, they will hint at having found something for you, but you only get it at the 10th and 20th won game.
You don't need to save any data to the Amiibo to get the gear if you're starting from scratch in Splatoon 3.